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    <title>UTas ePrints - Mercury(II) and Organomercury(II) Complexes of Thiols and Dithiols, Including British Anti-Lewisite</title>
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<meta content="Mercury(II) and Organomercury(II) Complexes of Thiols and Dithiols, Including British Anti-Lewisite" name="eprints.title" />
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<meta content="The dithiols 2,3-dimercapto-l-propanol (British anti-Lewisite) and 1,3-dimercapto-2propanol form complexes RHgS-SHgR (R = Me, Ph). The PhHg(II) complexes decompose in benzene and methanol at ambient temperature to form diphenylmercury. A 1:1 complex of Hg(II) with 1,3 dimercapto-2-propano1 is dimeric in pyridine. Infrared, Raman, and 1H NMR spectra of RHg(II) and Hg(II) dithiol complexes are compared with those of PhHgSR (R = Me, Et, H,
But, Ph, CH,CH20H) and Hg(SR')2 (R’ = Me, Et, But, Ph, CH2CH20H). Phenylmercury(II) thiolates have the coupling constant J(orthoH-199Hg) within the range 144-155 Hz. The complexes PhHgSR and Hg(SR”)z (R” = Et, But, Ph) are monomeric in chloroform; the chloroform insoluble complexes Hg(SR”')2 (R”’ = Me, CH,CH20H) and organomercury
(II) dithiolates are monomeric in pyridine. Aspects of
the use of British anti-Lewisite as an antidote for mercury poisoning are discussed." name="eprints.abstract" />
<meta content="1977" name="eprints.date" />
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T. W. Clarkson and V. DiStefano in “Drill’s Pharmacology
in Medicine”, J. R. DiPaIma and R. Joseph, Eds.,
McGraw-Hill, 4th Edn. (1971), Chapter 53.
A. Swensson and U. Ulfvarson, Irtt: Arch. Gewerbeputh.
Gewerbehva.. 24. 12 (1967).
M. Berlin and S. Ullberg, N&amp;e, 197, 84 (1963).
M. Berlin, L.-G. JerkseIl, and G. Nordberg, Actu Pharmaeol.
Toxicol., 23, 312 (1965).
M. Berlin and R. Rylander, J. Pharmacol. Exptl. Therap.,
146, 236 (1964).
J. R. Fitzsimmons and F. L. KozeIka, J. Pharmacol.
Exptl. Therup., 98, 8 (1950).
M. Berlin and T. Lewander, Actu Pharmacol. Toxicol.,
22, 1 (1965).
L. Magos, Brit. J. Industr. Med., 25, 152 (1968).
T. Norseth, Actu Pharmacol. Toxicol., 32, 1 (1973).
See, e.g. T. W. Clarkson, H. Small, and T. Norseth, Arch,
Environ. Health, 26. 173 (1973); J. Aaseth and T.
Norseth, Actu ~harnkol. T&amp;icoi, 35, 23 (1974); F.
Bakir, S. F. Damluji, L. Amin-Zaki, M. Murtadha, A.
Khalidi. N. Y. Al-Rawi. S. Tikriti. H. I. Dhahir. T. W.
Clark&amp;n, J. C. Smith, and R. A. Doherty, Science, 181,
230 (1973).
A. Gilman, R. P. Allen, F. S. Philips, and E. St. John, J.
Clin. Invest., 25, 549 (1946).
R. Benesch and R. E. Benesch, Arch. Biochem. Biophys.,
38, 425 (1952).
A. J. Canty, R. Kishimoto, G. B. Deacon and G. J.
Farquharson,Inorg. Chim. Acts, 20, 163 (1976).
J. F. Lehman, L. P. Barrack and R. A. Lehman, Science
113,410 (1951).
A. J. Canty and R. Kishimoto, Nature, 253, 123 (1975).
M. M. Koton, E. P. Moskvina, and F. S. Florinskii, Zh.
Obsh. Khim., 20, 2093 (1950); D. C. Gregg, H. A. Iddles,
and P. W. Stearns,J. Org. Chem., 16, 246 (1951).
H. Lecher. Chem. Ber.. 48. 1425 (1915).
A. M. Creighton, L. N. Owen and G. R. White, J. Chem.
Sot., 2375 (1961).
N. Iritani and Y. Hagihara, Chem. Abstr., 56, P1302Oi
(1962).
G. Sachs, Justus Liebig’s Annalen, 433, 154 (1923).
G. Leandri and D. Spinelli, Ann. Chim. (Rome), 49.
1885 (1959).
A. J. Canty and R. Kishimoto, Aust. J. Chem., 30, in
press (1977).
N. Herzfeld. C. K. Ingold. and H. G. Poole, J. Chem.
Sot., 316 (1946). -
D. C. Bradley and N. R. Kunchur. J. Chem. Phvs.. 40.
2258 (1964).-
_
N. R. Kunchur, Nature, 204,468 (1964).
See, e.g., A Shulman and F. P. Dwyer in “Chelating
Agents and Metal Chelates”, F. P.’ Dwyer and D. P.
MeIlor (Eds.), Academic Press, New York (1964), p. 388.
27 N. Iwasaki, J. Tomooka, and K. Toyoda. Bull. Chem.
Sot. Jap., 47, 1323 (1974).
28 P. Biscarini. L. Fusina and G. Nivellini. J. Chem. Sot.
Dalton, 214b (1974).
29 D. C. Bradley and N. R. Kunchur, Can. J. Chem., 43,
2786 (1965).
30 A. J. Carty, personal communication (1975).
31 R. A. Nyquist and J. R. Mann, Spectrochim. Acta,
Part A, 28, 511 (1972).
32 Y. S. Wong, N. J. Taylor, P. C. Chieh and A. J. Catty,
Chem. Comm.. 625 (1974).
33 N. J. Taylor, Y. S. .Wong, P. C. Chieh and A. J. Carty,
J. Chem. Sot. Dalton, 438 (1975).
34 N. N. Greenwood and K. Wade, J. Chem. SOL, 1130
(1960); N. S. Gill, R. H. Nuttall, D. E. Scaife and D. W.
A. Sharp, J. Inorg. Nucl. Chem., 18, 79 (1961; S. Akyiiz,
A. B. Dempster, R. L. Morehouse and S. Suzuki, J.
Molec. Struct., 17, 105 (1973).
35 V. S. Petrosyan and 0. A. Reutov, Izv. Akad. Nauk
SSSR, Ser. Khim., 1962 (1968).
36 W. McFarlane,J. Chem. Sot. A, 2280 (1968).
37 F. A. L. Anet and J. L. Sudmeier, J. Magn. Resort., I,
124 (1969); H. F. Henneike, J. Am. Chem. Sot.. 94.
5945 (1972).
38 R. D. Bach, A. T. Weibel, W. Schmonsees, and M. D.
Glick, Chem. Comm., 961 (1974).
39 A. J. Bloodworth, J. Chem. Sot. C, 205 1 (1970).
40 L. G. Kuz’mina, N. G. Bokii, Y. T. Struchkov, D. N.
Kravtsov, and E. M. Rokhlina, Zh. Strukt. Chim., 15, 491
(1974); J. Struct. Chem., 15, 419 (1974).
41 D. Grdenic, Quart. Rev., 19, 303 (1965).
42 L. Pauling, “The Nature of the Chemical Bond”, 3rd
Ed., Cornell University Press, Ithaca, New York (1960)
p. 260.
43 J. H. S. Green, Spectrochim. Acta, Part A, 24, 863
(1968).
44 L. F. Sytsma and R. J. Kline, J. Organometal. Chem., 54,
15 (1973).
45 J. V. Hatton, W. G. Schneider and W. Siebrand, J. Chem.
Phys., 39, 1330 (1963); P. G. Simpson, T. E. Hopkins
and R. Haque, J. Phys. Chem., 77, 2282 (1973); D. L.
Rabenstein and M. T. Fairhurst, J. Am. Chem. Sot.. 97,
2086 (1975); Y. Hojo, Y. Sugiura and H. Tanaka, J.
Inorg. Nucl. Chem., 38, 641 (1976); Y. Sugiura, Y. Hojo,
Y. Tamai and H. Tanaka, J. Am. Chem. Sot., 98, 2339
(1976); A. J. Canty and A. Marker, Aust. J. Chem., 29,
1383 (1976).
46 A. J. Canty and R. S. Parsons, unpublished results.
47 V. L. Miller, P. A. Klavano and E. Csonka, Toxicol.
Applied Pharmacol., 2, 344 (1960); J. C. Gage, Brit.
J. Industr. Med., 21, 197 (1964); J. W. Daniel and I. C.
Gage, Biochem. J., 122, 24P, (1971); J. W. Daniel, J. C.
Gage, and P. A. Lefevre, Biochem., J., 129, 961 (1972).
48 L. Magos, Brit. J. Zndustr. Med., 25, 315 (1968).
49 M. Berlin, L. G. Jerksell and H. von Ubisch, Arch.
Environ. Health, 12, 33 (1966)." name="eprints.referencetext" />
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<meta content="The dithiols 2,3-dimercapto-l-propanol (British anti-Lewisite) and 1,3-dimercapto-2propanol form complexes RHgS-SHgR (R = Me, Ph). The PhHg(II) complexes decompose in benzene and methanol at ambient temperature to form diphenylmercury. A 1:1 complex of Hg(II) with 1,3 dimercapto-2-propano1 is dimeric in pyridine. Infrared, Raman, and 1H NMR spectra of RHg(II) and Hg(II) dithiol complexes are compared with those of PhHgSR (R = Me, Et, H,
But, Ph, CH,CH20H) and Hg(SR')2 (R’ = Me, Et, But, Ph, CH2CH20H). Phenylmercury(II) thiolates have the coupling constant J(orthoH-199Hg) within the range 144-155 Hz. The complexes PhHgSR and Hg(SR”)z (R” = Et, But, Ph) are monomeric in chloroform; the chloroform insoluble complexes Hg(SR”')2 (R”’ = Me, CH,CH20H) and organomercury
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    <h1 class="ep_tm_pagetitle">Mercury(II) and Organomercury(II) Complexes of Thiols and Dithiols, Including British Anti-Lewisite</h1>
    <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Kishimoto, R.</span> (1977) <xhtml:em>Mercury(II) and Organomercury(II) Complexes of Thiols and Dithiols, Including British Anti-Lewisite.</xhtml:em> Inorganica Chimica Acta, 24 . pp. 109-122. ISSN 0020-1693</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2812/1/ICA1977_2C_109.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2812/1/ICA1977_2C_109.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />1310Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="3869" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1016/S0020-1693(00)93859-3">http://dx.doi.org/10.1016/S0020-1693(00)93859-3</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The dithiols 2,3-dimercapto-l-propanol (British anti-Lewisite) and 1,3-dimercapto-2propanol form complexes RHgS-SHgR (R = Me, Ph). The PhHg(II) complexes decompose in benzene and methanol at ambient temperature to form diphenylmercury. A 1:1 complex of Hg(II) with 1,3 dimercapto-2-propano1 is dimeric in pyridine. Infrared, Raman, and 1H NMR spectra of RHg(II) and Hg(II) dithiol complexes are compared with those of PhHgSR (R = Me, Et, H,&#13;
But, Ph, CH,CH20H) and Hg(SR')2 (R’ = Me, Et, But, Ph, CH2CH20H). Phenylmercury(II) thiolates have the coupling constant J(orthoH-199Hg) within the range 144-155 Hz. The complexes PhHgSR and Hg(SR”)z (R” = Et, But, Ph) are monomeric in chloroform; the chloroform insoluble complexes Hg(SR”')2 (R”’ = Me, CH,CH20H) and organomercury&#13;
(II) dithiolates are monomeric in pyridine. Aspects of&#13;
the use of British anti-Lewisite as an antidote for mercury poisoning are discussed.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Additional Information:</th><td valign="top" class="ep_row">The definitive version is available at http://www.sciencedirect.com&#13;
</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/250200.html">250000 Chemical Sciences &gt; 250200 Inorganic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2812</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">07 Jan 2008 08:30</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">09 Jan 2008 02:30</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2812;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2812">item control page</a></p>
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